6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium tris(thiocyanato-κN)cuprate(I)
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چکیده
The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-inter-acting cations and trigonal-planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 Å. The Cu(I) atom is displaced by 0.019 (2) Å out of the N(3) triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45.
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6,7-Dihydro-3H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione
In the title compound, C(15)H(12)N(2)O(2), the seven-membered ring bearing the three methyl-ene C atoms displays a puckered conformation, with the methyl-ene C atoms deviating from the plane of the benzene ring by 0.05 (1), 0.98 (1) and 1.04 (1) Å. The phenanthroline unit is not planar; the dihedral angles between this benzene ring and the other pyridyl rings are 9.62 (4) and 9.31 (4)°. The cry...
متن کاملBis(2-chloro-1,10-phenanthroline-κ2 N,N′)(thiocyanato-κN)zinc (2-chloro-1,10-phenanthroline-κ2 N,N′)tris(thiocyanato-κN)zincate
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متن کاملcis-Bis(1,10-phenanthroline-κ2 N,N′)bis(thiocyanato-κN)magnesium(II)
The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro-thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa-hedral geometry containing four N atoms from two 1,10-phenanthroline mol-ecules and two N atoms fro...
متن کامل(2-Methoxy-1,10-phenanthroline-κ2 N,N′)bis(thiocyanato-κN)zinc(II)
In the title complex, [Zn(NCS)(2)(C(13)H(10)N(2)O)], the Zn(II) ion is in a distorted tetra-hdral ZnN(2)Cl(2) coordination environment. In the crystal structure, there is a weak π-π stacking inter-action between adjacent 1,10-phenanthroline rings, with a pyridine centroid-centroid distance of 3.6620 (15) Å.
متن کامل(4,7-Diphenyl-1,10-phenanthroline-κ2 N,N′)dimethylbis(thiocyanato-κN)tin(IV)
In the title compound, [Sn(CH(3))(2)(NSC)(2)(C(24)H(16)N(2))], a 1:1 adduct of dimethyl-tin diisothio-cyanate with 4,7-diphenyl-1,10-phenanthroline, the Sn(IV) atom shows a slightly distorted octa-hedral SnC(2)N(4) coordination. The methyl groups are trans to each other in the octa-hedron surrounding the metal atom [C-Sn-C = 176.61 (12)°].
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